A new stable monomeric lead(ii) dithiolate Pb(SCH(2)CH(2)NMe(2))(2): an interplay between a dynamic "flip-flop" process in solution and conformational isomerism in the solid-state.

نویسندگان

  • Victor N Khrustalev
  • Rinat R Aysin
  • Irina V Borisova
  • Alexander S Peregudov
  • Larissa A Leites
  • Nikolai N Zemlyansky
چکیده

The structure and dynamic behaviour of monomeric lead(ii) dithiolate Pb(SCH(2)CH(2)NMe(2))(2) are studied by multi-nuclear NMR, IR and Raman spectroscopy in solution, as well as variable-temperature Raman spectroscopy and X-ray diffraction analysis in the solid-state, revealing an unusual dynamic "flip-flop" process in solution and reversible conformational isomerism of the chelated five-membered rings in the solid-state.

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عنوان ژورنال:
  • Dalton transactions

دوره 39 40  شماره 

صفحات  -

تاریخ انتشار 2010